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Beilstein J. Org. Chem. 2015, 11, 1079–1088, doi:10.3762/bjoc.11.121
Graphical Abstract
Figure 1: Examples of hybrid heteroarenes from the class of indolizines.
Figure 2: Starting 4-pyridylpyrimidines 6–8.
Scheme 1: The synthesis of new pyrimidinium bromides 11 and pyrrolo[1,2-c]pyrimidines 12.
Figure 3: The 1H NMR spectra (DMSO-d6) of 4-(2-pyridyl)pyrimidine (6) and the corresponding bromides 11a–e (t...
Scheme 2: The synthesis of new pyridinium bromides 13a,b and indolizines 14a–f.
Scheme 3: The synthesis of the new pyridinium bromides 15 and 7-pyrimidylindolizines 16a–f.
Scheme 4: Reaction mechanism.
Figure 4: Molecular and crystal structures of 6 (a,b) and 8 (c,d). The molecules are located on centers of in...